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HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE
https://nipr.repo.nii.ac.jp/records/3536
https://nipr.repo.nii.ac.jp/records/353663a09d15-bb0e-4841-848e-14a9ce60aa8f
名前 / ファイル | ライセンス | アクション |
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KJ00000767744.pdf (95.7 kB)
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Item type | 紀要論文(ELS) / Departmental Bulletin Paper(1) | |||||
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公開日 | 1987-09-01 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ページ属性 | ||||||
内容記述タイプ | Other | |||||
内容記述 | P(論文) | |||||
記事種別(英) | ||||||
en | ||||||
ABSTRACT | ||||||
論文名よみ | ||||||
その他のタイトル | HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE | |||||
著者名よみ |
ハタケヤマ, シロウ /
× ハタケヤマ, シロウ / |
|||||
著者名(英) |
HATAKEYAMA, Shiro
× HATAKEYAMA, Shiro× LEU, Ming-Taun |
|||||
著者所属(英) | ||||||
en | ||||||
National Institute for Environmental Studies | ||||||
著者所属(英) | ||||||
en | ||||||
Jet Propulsion Laboratory, California Institute of Technology | ||||||
抄録(英) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Reactions of chlorine nitrate (ClONO_2) with HCl and H_2O have been investigated using a 320-L Pyrex chamber and long-path FT-IR spectroscopy. Both reactions showed highly heterogeneous nature. Obtained upper limit rate constants fot homogeneous reactions were 8.4×(10)^<-21> and 3.4×(10)^<-21>(cm)^3 molec^<-1>s^<-1> for ClONO_2+HCl and ClONO_2+H_2O, respectively, at 296±2K at 730 torr total pressure. The yield of HNO_3 from both the reactions was 1.05±0.09 and 0.86±0.08,respectively. Formation of HOCl was confirmed in the latter reaction. No synergistic effect between HCl and H_2O was observed for the reaction with ClONO_2. The kinetic behavior of the reaction ClONO_2+H_2O was well described by simple first-order kinetics while the behavior of the reaction ClONO_2+HCl was found to obey the Langmuir adsorption isotherm. | |||||
雑誌書誌ID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10756213 | |||||
書誌情報 |
Proceedings of the NIPR Symposium on Polar Meteorology and Glaciology 巻 1, p. 148, 発行日 1987-09 |