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"relation": {}, "relation_version_is_last": true, "title": ["ヨウ化銅クラスターを骨格に含む新規混合金属一次元配位高分子の合成と結晶構造"], "weko_shared_id": -1}
ヨウ化銅クラスターを骨格に含む新規混合金属一次元配位高分子の合成と結晶構造
https://kindai.repo.nii.ac.jp/records/18487
https://kindai.repo.nii.ac.jp/records/184877471482c-b1e9-49a5-8ac1-35ec1b5cc0fd
名前 / ファイル | ライセンス | アクション |
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AN10074306-20170228-0011.pdf (2.4 MB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2017-06-20 | |||||
タイトル | ||||||
タイトル | ヨウ化銅クラスターを骨格に含む新規混合金属一次元配位高分子の合成と結晶構造 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and Crystal Structures of New Mixed-Metal 1-D Coordination Polymers including a Copper-Iodide Cluster Unit | |||||
著者 |
谷嶋, 晃樹
× 谷嶋, 晃樹× 安間, 晴穂× 大久保, 貴志× 前川, 雅彦× 黒田, 孝義 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | mixed-metal coordination polymer, crystal structure, dithiocarbamate ligand, pentanuclear Cu(I) cluster, absorption spectra, photoelectron spectroscopy | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
TANISHIMA,Koki | ||||||
著者(英) | ||||||
en | ||||||
ANMA,Haruho | ||||||
著者(英) | ||||||
en | ||||||
OKUBO,Takashi | ||||||
著者(英) | ||||||
en | ||||||
MAEKAWA,Masahiko | ||||||
著者(英) | ||||||
en | ||||||
KURODA-SOWA,Takayoshi | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kindai University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kindai University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kindai University | ||||||
著者所属(翻訳) | ||||||
Research Institute for Science and Technology, Kindai University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kindai University | ||||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学総合研究所 | |||||
書誌情報 |
理工学総合研究所研究報告 en : Annual reports by Research Institute for Science and Technology 号 29, p. 11-16, 発行日 2017-02-28 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09162054 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Novel mixed-metal Cu(I)-Ni(Ⅱ) coordination polymers having an infinite one-dimensional (1D) structure, {[CuI5NiIⅡ5(Pip-dtc)2(C2H5CN)]・CHCl3}n (1) and {[CuI5CuⅡI5(Hm-dtc)2(C2H5CN)]・CHCl3}n (2) (Pip-dtc- = piperidine dithiocarbamate and Hm-dtc- = hexamethylene dithiocarbamate), have been prepared and structurally characterized via X-ray diffraction. These complexes comprised a mononuclear Ni(Ⅱ) unit, CuⅡL2, and a pentanuclear Cu(I) cluster unit, CuI5I5(C2H5CN)2. The energy states of these coordination polymers were investigated via photoelectron spectroscopy and diffuse reflectance spectroscopy, which indicated the formation of the narrow bands based on the weak orbital’s overlap between the mononuclear Ni(Ⅱ) unit and the pentanuclear Cu(I) cluster unit. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |